Read Molecular Gastronomy: Exploring the Science of Flavor Online
Authors: Hervé This
Tags: #Cooking, #General, #Methods, #Essays & Narratives, #Special Appliances, #Science, #Chemistry, #Physics, #Technology & Engineering, #Food Science, #Columbia University Press, #ISBN-13: 9780231133128
ists have decoded the alphabet of algal polysaccharides, it remains for them to
learn how to form words and put them together.
Algal Fibers
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58
Cheeses
Commercial protection requires several kinds of analysis.
t o p r o t e c t t h e i r c a m e m b e r t s and other raw milk cheeses against leg-
islation that would prohibit the use of raw milk in fabrication, countries such
as France must demonstrate the gastronomic superiority of these cheeses by
comparison with ones made from pasteurized milk. To do this they must per-
form a detailed comparison of the chemical composition, texture, and aroma of
the different types, which will take quite a while. In the meantime, the Institut
National de la Recherche Agronomique and the Comité Interprofessionnel du
Gruyère de Comté, in collaboration with food research institutes elsewhere
in Europe, have been analyzing cheese with the aid of a very efficient system:
human beings.
The chemical analysis of cheeses, as by chromatography, often is insuffi-
cient. As a device for detecting trace amounts of molecular compounds, which
sometimes are aromatically preponderant, the human nose has no rival. Nor
are measurements of mechanical properties very helpful in characterizing cer-
tain cheeses that are pasty, crumbly, and heterogeneous.
On the other hand, tasting—an essentially subjective activity—integrates
various pieces of sensory information that human beings sometimes have a
hard time dissociating. A group of experts in the sensory analysis of cheeses,
assembled under the auspices of a European Union program called Food
Link Agro-Industrial Research (flair), has sought to set standards for the
training of tasting juries and to define norms for characterizing hard and
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semihard cheeses. Six cheeses awarded a protected designation of origin were
tested: Comté (from the French Jura), Beaufort (from the French Savoie),
Parmagiano-Reggiano and Fontina (Italy), Mahon (Spain), and Appenzeller
(Switzerland).
The Texture of Cheeses
The texture of cheese is a crucial property, as anyone who has eaten a chalky
Camembert or a rubbery Gruyère knows. Unlike the organoleptic qualities of
shortbread biscuits, gum arabic candies, or puffed cocktail crackers, those of
cheeses cannot be described in terms of a single textural characteristic, for the
flavor of a cheese depends in complex ways on its overall texture.
The European laboratories participating in the flair study evaluated the
texture of the six selected cheeses by comparing their superficial, mechanical,
and geometric characteristics in addition to various sensations they produce in
the mouth. To specify perceptions and intensities, the researchers character-
ized the samples in terms of a reference class of basic textures associated with
a particular kind of apple, a cracker, a banana peel, and so on.
In the 1960s American food researchers proposed a general classification
of the textural properties of foods, but the study of cheeses has since shown it
to be inadequate. Which sensory characteristics must be considered in order to
define the texture of a food? And how can they be systematically recognized?
Specialists in sensory analysis have devised a range of methods for evaluat-
ing products: analysis by untrained judges, by trained judges on the basis of
predetermined categories, and by trained judges using intuitive criteria. The
attempt to establish international norms required a strict methodology. The
protocol finally chosen involved predetermined categories with trained judges
conducting blindfold tests.
Sensory evaluation consisted of the following steps: looking at the sample,
touching it, chewing it, deforming it, and shaping it into a ball before swal-
lowing. Because the overall assessment of texture was to be made with refer-
ence to surface, mechanical, geometric, and other objective measurements,
each phase of tasting was classified under one of these four categories. The
intensity of each sensation was evaluated on a scale of 1 to 7, with a minimum
of three basic textures serving as points of reference. Tasting was done at a
temperature of 16°c (61°f).
Cheeses
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Parallelepipedal slices of cheese having an area of 150 square centimeters
(about 24 square inches) and a thickness of 2 centimeters (about three-quar-
ters of an inch) were visually inspected to assess the smoothness of their sur-
faces and the presence of any openings, tears, crystalline deposits, and droplets
of water or oil. Tactile information regarding superficial quality was collected
next: Samples were put on a plate, and the judges ran their index fingers over
each slice to feel the grain and the degree of moistness. Mechanical character-
istics were noted by examining strips 1.5 cm (about half an inch) wide and 5–8
cm (about 2–3 inches) long that had been cut along the grain of the cheese. The
judges then evaluated elasticity (by pressing down with the thumb), firmness
(by gently pressing down with the teeth), deformability (the maximum defor-
mation achieved before breaking), friability, and adhesivity. Finally, geometric
characteristics related to the shape, size, and nature of the particles perceived
in the course of chewing (sandiness, granularity, fibrousness, and so on) were
analyzed, along with other textural characteristics resulting from complex and
residual perceptions such as solubility, impression of humidity (dry or moist),
and astringency.
Cultural References
The products used as bases for comparison in evaluating all these charac-
teristics were chosen because they are readily available in European countries
and because, in the case of prepared dishes, they are simple to make using
standardized procedures. For example, roughness was determined by compari-
son with the outer surfaces of a Granny Smith apple, a banana peel, a ladyfin-
ger, and a Breton cake; solubility was determined by comparison with a long
madeleine, a cooked egg yolk, and a small meringue; and so on.
In the case of hard and semihard cheeses, further study will be needed to
examine correlations between sensory descriptions of texture and mechani-
cal and biochemical analyses. New European Union research programs have
been proposed for soft cheeses, for there remains a great deal to learn about
the reasons for the distinctive character of raw milk products. However, Cam-
embert is not included in these programs, for lack of a commercial sponsor
(in Europe the costs of such research fall on industry). For the moment, then,
Camembert’s superiority is a fact only in the minds of connoisseurs.
202 | investigations a nd mod el s
59
From Grass to Cheese
Diet contributes to the quality of cows’ milk cheeses.
l e t e r r oi r
— t h e l a n d. For several years food producers have been talk-
ing of nothing else, often out of a desire to protect or expand their markets.
If they are to be believed, there is a special relationship between a region and
its products; no version of a product made elsewhere is as good as the origi-
nal, which for this reason is the only one to merit a protected designation of
origin.
Agronomic analysis has demonstrated the effects of climate, soil, and ex-
posure in the case of wine, but cheese proved to be a trickier proposition.
Working with producers in the northern French Alps and the Massif Cen-
tral, Jean-Baptiste Coulon and his colleagues at the Institut National de la
Recherche Agronomique station at Clermont-Ferrand recently succeeded not
only in illuminating the relationship between the land and the quality of its
cheeses but also in proposing objective criteria for according them certain
legal protections.
Taste and Reôn
What makes a cheese good? The distinctive characteristics of a cheese may
result from the physical features of the region in which it is produced, the
types of animals that provide the milk from which it is made, and the people
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who make it. Producers who talk about
terroir
emphasize the importance of the
cows’ environment and, in particular, of their diet: green grass, hay, and silage
(wet grass stored in silos, where it ferments). Does this diet really determine
the quality of a cheese?
The first attempts to answer this question, beginning in 1990, involved
twenty makers of Gruyère in the Franche-Comté region of France and revealed
a significant correlation between the taste of their products and the geographic
site of their operations. In other words, one can give a rigorous definition of
what “raw milk” means in Franche-Comté. Subsequent analysis of the volatile
components of Gruyère made in Switzerland showed that mountain pasture
cheeses are distinct from those of the plains: Fragrant molecules belonging
to the class of terpenes (limonene, pinene, nerol), for example, are present in
much higher quantities in mountain pasture cheeses. What accounts for these
variations? Agronomists initially supposed that they resulted from differences
in vegetation.
However, in these early studies methods of production and the character-
istics of the animals had not been taken into account. Would the observed
differences not have been found if the type of cow or the type of fabrication
had been modified? In other words, can cheeses typical of mountain pastures
be obtained by treating milk from alpine cows with production methods used
at lower elevations?
The
of Reblochon
Coulon and his colleagues decided to use Reblochon as a case study. Ex-
amining samples taken from several producers who used comparable fabrica-
tion techniques, they demonstrated that dietary characteristics determined the
sensory characteristics of the cheese. They showed that cows grazing in two
different parts of the same mountain pasture—one a southerly slope covered
mainly by
Dactylis glomerata
and
Festuca rubra
and the other a northerly slope
sparsely planted with
Agrostys vulgaris
and
Nardus stricta
along with unproduc-
tive patches of moss and
Carex davalliana
—gave cheeses that differed notably
with regard to taste and color. The cheeses from the south-facing precincts
were shinier and less yellow, and their taste was more intense, fruitier, and
spicier.
204 | investigations a nd mod el s
The sensory differences between cheeses may be a direct result of the mo-
lecular content of the cows’ forage. Carotene, which is present in vegetables,
gives cheese their color. It is also known that ingestion of certain subtoxic
plants (such as
Ranonculus
and
Caltha palustris,
which seem to be more com-
mon in north-facing mountain pastures) changes the cellular permeability of
mammary tissue and facilitates passage into the milk of enzymes that alter the
quality of cheese made from it. Moreover, it is possible that microorganisms
typically found in the soil of grazing lands may have a significant influence on
the characteristics of cheeses, but this remains to be demonstrated.
The E‡ects of Silage
Finally, more recent studies have examined the effects of silage, which
in certain regions is a matter of controversy (some say it produces mediocre
cheese). The new studies involved more than twenty farms producing raw milk
Saint-Nectaire of recognized quality. More than sixty cheeses were analyzed by
means of sensory studies, with judges instructed to evaluate taste, odor, and
texture.
It was discovered that the principal differences between these cheeses re-
sulted from methods of fabrication and the diet of the cows rather than the
manner in which their forage was stored. In particular, cows feeding on hay
did not always produce cheeses that differed notably from ones made from
the milk of cows that were fed on silage. The stocking of forage under con-